Cost-effective pathway for spent catalyst recyle at Dung Quat refinery and Phu My fertilizer plant
Abstract
As the number of refineries and petrochemical plants grows in Vietnam, the amount of spent catalysts and waste material is also increasing sharply. Specifically, more than 500 tons of 8 different types of spent catalysts at Phu My Fertilizer Plant and approximately 6,000 tons of 9 types of catalysts and 6 types of adsorbents at Dung Quat Refinery are disposed each year. Despite their value, most of these spent catalysts have so far been disposed of by burying in landfills. In this paper, the authors, on the basis of reviewing the different methods of spent catalyst treatment in the world and catalyst assessment in the laboratory, recommend the most suitable method for treatment of each spent catalyst of Phu My Fertilizer Plant and Dung Quat refinery in terms of technical and economic aspects.
References
M.Marafi , A.Stanislaus and E.Furimsky. Chapter 4 - Catalyst deactivation. Handbook of Spent hydroprocessing catalysts. Elsevier: Amsterdam. 2010: p. 51 - 92.
M.Marafi , A.Stanislaus and E.Furimsky. Chapter 11 - Metal reclamation from spent hydroprocessing catalysts. Handbook of Spent hydroprocessing catalysts. Elsevier: Amsterdam. 2010: p. 269 - 315.
M.Marafi , A.Stanislaus and E.Furimsky. Chapter 5 - Environmental and safety aspects of spent hydroprocessing catalysts. Handbook of Spent hydroprocessing catalysts. Elsevier: Amsterdam. 2010: p. 93 - 120.
M.Marafi , A.Stanislaus and E.Furimsky. Chapter 6 - Regeneration. Handbook of Spent hydroprocessing catalysts. Elsevier: Amsterdam. 2010: p. 121 - 190.
J.A.Moulijn, A.E.van Diepen and F.Kapteijn. Deactivation and Regeneration. Handbook of Heterogeneous catalysis. Wiley-VCH Verlag GmbH & Co. KGaA. 2008.
D.L.Trimm. The regeneration or disposal of deactivated heterogeneous catalysts. Applied Catalysis A: General. 2001; 212(1 - 2): p. 153 - 160.
E.Furimsky and F.E.Massoth. Introduction. Catalysis Today. 1993; 17(4): p. 537 - 659.
M.Marafi and A.Stanislaus. Options and processes for spent catalyst handling and utilization. Journal of Hazardous Materials. 2003; 101(2): p. 123 - 132.
M.Marafi , A.Stanislaus and E.Furimsky. Chapter 9 - New catalysts from spent catalysts. Handbook of Spent hydroprocessing catalysts. Elsevier: Amsterdam. 2010: p. 231 - 257.
N.Su, Z.-H.Chen and H.-Y.Fang. Reuse of spent catalyst as fine aggregate in cement mortar. Cement and Concrete Composites. 2001; 23(1): p. 111 - 118.
R.K.Clifford. Spent catalyst management. 1997.
R.P.Silvy. Future trends in the refining catalyst market. Applied Catalysis A: General. 2004; 261(2): p. 247 - 252.
Global markets catalyst regeneration. BCC Research. 2/2012.
G.J.Yeh et al. Improve usage of regenerated refining catalysts. Hydrocarbon processing. 2010: p. 63 - 67.
Porocel. Catalyst regeneration & resale - A business opportunity. Annual workshop 2011 on waste & emissions management in process industry. Lodhi Road, New Delhi. 2011.
Henry Nowicki, George Nowicki, Barbara Sherman. GAED determination of activated carbon in fly ash from coal fired electric power plants. Gravimetric adsorption energy distribution. 2007.

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