Synthesis and characterisation of decylphosphonic acid doped polyaniline (PANI-DPA) prepared by emulsion polymerisation

  • Phan Thế Anh
  • F.X. Perrin
  • Nguyen Dinh Lam
Keywords: Polyaniline, decylphosphonic acid, direct emulsion polymerisation, inverse emulsion polymerisation

Abstract

The combination of polyaniline (PANI), a conductive polymer, and a corrosion inhibitor has been studied to manufacture anti-corrosion coatings. This paper introduces some research results on PANI-DPA, a new material combining polyaniline with decylphosphonic acid, an environmentally friendly corrosion inhibitor, synthesised via two emulsion methods: in direct and inverse emulsions. The polymerisation was performed at room temperature by using ammonium peroxydisulfate (APS) as oxidant and decylphosphonic acid (DPA) as surfactant. The diff erences in the properties of synthesised PANI-DPA from the two methods were studied in detail. The structure of nano-bars (100-200nm) and nanofibres (50-100nm) were observed in the inverse emulsion and direct emulsion system, respectively.

References

J.P.Folkers, C.B.Gorman, P.E.Laibinis, S.Buchholz, G.M.Whitesides, and R.G.Nuzzo. Self-assembled monolayers of long-chain hydroxamic acids on the native oxide of metals. Langmuir. 1995; 11(3): p. 813 - 824.

S.Marcinko, A.Y.Fadeev. Hydrolytic stability of organic monolayers supported on TiO2 and ZrO2. Langmuir. 2004; 20(6): p. 2270 - 2273.

A.Paszternák, I.Felhősi, Z.Pászti, E.Kuzmann, A.Vértes, E.Kálmán, L.Nyikos. Surface analytical characterization of passive iron surface modified by alkylphosphonic acid layers. Electrochimica Acta. 2010; 55(3): p. 804 - 812.

J. E.Pereira da Silva, S.I.Córdoba de Torresi, R.M.Torresi. Polyaniline acrylic coatings for corrosion inhibition: The role played by counter-ions. Corrosion Science. 2005; 47(3): p. 811 - 822.

C.Queff élec, M.Petit, P.Janvier, D.A.Knight, B.Bujoli. Surface modification using phosphonic acids and esters. Chemical Reviews. 2012; 112(7): p. 3777 - 3807.

P.Ghosh, S.K.Siddhanta, S.R.Haque, A.Chakrabarti. Stable polyaniline dispersions prepared in nonaqueous medium: Synthesis and characterization. Synthetic Metals. 2001; 123(1): p. 83 - 89.

M. T.Nguyen, P.Kasai, J.L.Miller, A.F.Diaz. Synthesis and properties of novel water-soluble conducting polyaniline copolymers. Macromolecules. 1994; 27(13): p. 3625 - 3631.

Wen-Yue Zheng, Kalle Levon, Jukka Laakso, Jan-Eric Oesterholm. Characterization and solid-state properties of processable n-alkylated polyanilines in the neutral state. Macromolecules. 1994; 27(26): p. 7754 - 7768.

J.Anand, S.Palaniappan, D.N.Sathyanarayana. Conducting polyaniline blends and composites. Progress in Polymer Science. 1998; 23(6): p. 993 - 1018.

A. Pud, N.Ogurtsov, A.Korzhenko, G.Shapoval. Some aspects of preparation methods and properties of polyaniline blends and composites with organic polymers. Progress in Polymer Science. 2003; 28(12): p. 1701 - 1753.

S.Xing, Y.Chu, X.Sui, and Z.Wu. Synthesis and characterization of polyaniline in CTAB/hexanol/water reversed micelle. Journal of Materials Science. 2005; 40(1): p. 215 - 218.

J.-E.Österholm, Y.Cao, F.Klavetter, P.Smith. Emulsion polymerization of aniline. Synthetic Metals. 1993; 55(2-3): p. 1034 - 1039.

Phan Thế Anh, Nguyễn Đình Lâm, F.X.Perrin. Tổng hợp polyaniline theo phương pháp trùng hợp nhũ tương đảo. Tạp chí Khoa học và Công nghệ Đại học Đà Nẵng. 2011; 3(44): p. 12 - 19.

F.X.Perrin, Phan The Anh, Nguyen Dinh Lam. Preparation and characterization of polyaniline in reversed micelles of decylphosphonic acid for active corrosion protection coatings. European Polymer Journal. 2015; 66: p. 253 - 265.

Z.Ping. In situ FTIR-attenuated total reflection spectroscopic investigations on the base-acid transitions of polyaniline. Base-acid transition in the emeraldine form of polyaniline. Journal of Chemical Society, Faraday Transactions. 1996; 92(17): p. 3063 - 3067.

J.Tang, X.Jing, B.Wang, F.Wang. Infrared spectra of soluble polyaniline. Synthetic Metals. 1988; 24(3): p. 231 - 238.

Miroslava Trchová, Ivana Šeděnková, Eva Tobolková, Jaroslav Stejskal. FTIR spectroscopic and conductivity study of the thermal degradation of polyaniline films. Polymer Degradation and Stability. 2004; 86(1): p. 179 - 185.

S.Quillard, G.Louam, J.P.Buisson, M.Boyer, M.Lapkowski, A.Pron, S.Lefrant. Vibrational spectroscopic studies of the isotope effects in polyaniline. Synthetic Metals. 1997; 84(1 - 3): p. 805 - 806.

S.Quillard, G.Louarn, S.Lefrant, A.G.Macdiarmid. Vibrational analysis of polyaniline: A comparative study of leucoemeraldine, emeraldine, and pernigraniline bases. Physical Review B. 1994; 50(17): p. 12496 - 12508.

M.Cochet, G.Louarn, S.Quillard, M.I.Boyer, J.P.Buisson, S.Lefrant. Theoretical and experimental vibrational study of polyaniline in base forms: non-planar analysis. Journal of Raman Spectroscopy. 2000; 31(11): p. 1029 - 1039.

Y.Furukawa, F.Ueda, Y.Hyodo, I.Harada, T.Nakajima, T.Kawagoe. Vibrational spectra and structure of polyaniline. Macromolecules. 1988; 21(5): p. 1297 - 1305.

E.Kang. Polyaniline: A polymer with many interesting intrinsic redox states. Progress in Polymer Science. 1998; 23(2): p. 277 - 324.

E.T.Kang, K.G.Neoh, T.C.Tan, S.H.Khor, K.L.Tan. Structural studies of poly(p-phenyleneamine) and its oxidation. Macromolecules. 1990; 23(11): p. 2918 - 2926.

J.-C. Chiang, A.G.MacDiarmid. Polyaniline: Protonic acid doping of the emeraldine form to the metallic regime. Synthetic Metals. 1986; 13(1 - 3): p. 193-205.

H.S.O.Chan, S.C.Ng, P.K.H.Ho. Polyanilines doped with phosphonic acids: Their preparation and characterization. Macromolecules. 1994; 27(8): p. 2159 - 2164.

Y.Şahin, K.Pekmez, A.Yıldız. Electrochemical synthesis of self-doped polyaniline in fluorosulfonic acid/acetonitrile solution. Synthetic Metals. 2002; 129(2): p. 107 - 115.

J.Stejskal, R.G.Gilbert. Polyaniline. Preparation of a conducting polymer (IUPAC Technical Report). Pure and Applied Chemistry. 2002; 74(5): p. 857 - 867.

Yong Cao, Jinjin Qiu, Paul Smith. Effect of solvents and co-solvents on the processibility of polyaniline: Solubility and conductivity studies. Synthetic Metals. 1995; 69(1 - 3): p. 187 - 190.

S.Bhadra, N.K.Singha, D.Khastgir. Effect of aromatic substitution in aniline on the properties of polyaniline. European Polymer Journal. 2008; 44(6): p. 1763 - 1770.

N.Plesu, G.Ilia, A.Pascariu, G.Vlase. Preparation, degradation of polyaniline doped with organic phosphorus acids and corrosion essays of polyaniline-acrylic blends. Synthetic Metals. 2006; 156(2 - 4): p. 230 - 238.

Published
2016-01-29
How to Cite
Anh, P. T., Perrin, F., & Lam, N. D. (2016). Synthesis and characterisation of decylphosphonic acid doped polyaniline (PANI-DPA) prepared by emulsion polymerisation. Petrovietnam Journal, 1, 47-53. Retrieved from http://www.pvj.vn/index.php/TCDK/article/view/472
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Articles