Studying the composition of hydrocarbons of bitumen in magmatic rocks from North Khakasia (Russia)

  • Vu Van Hai
  • O.V. Serebrennikova
Keywords: Natural bitumen, basalts, aryl isoprenoids, polyphenyl, phenyl-substituted, steranes, terpanes

Abstract

Three natural bitumen samples and one sample of bitumen extract from basalt rocks in North Khakasia were chosen for this study. In all bitumen identified, hydrocarbons include alkanes, alkylcyclohexanes, pregnanes, steranes, sesqui-, tri- and pentacyclic terpanes, alkylbenzenes, bi-, tri- and tetracyclic condensed aromatic structures. Polyphenyls (up to five phenyl rings), phenyl-substituted naphthalenes, phenanthrenes and pyrenes, binaphthalene, diphenylalkanes, ethylalkylphenyl, and tribenzocycloheptanes are found in solid bitumen and dispersed organic matter of basalt. Analysis of the composition of hydrocarbons indicates that the pyrolysis processes by contact with molten magma had an influence on the bitumen composition in the basalt and the specific conditions of the original organic matter accumulation and biodegradation had an influence on the viscous bitumen.

References

Nils-Martin Hanken, Malene Dolberg Hansen, Jesper Kresten Nielsen, Snorre Olaussen, Bjørn Buchardt, Tor Eggebø, Reidar Steinsland. The presence of hydrocarbons in Southeast Norway. GEP-01 General contributions to petroleum geoscience, presented at the 33rd International Geological Congress, Oslo. 6 - 14 August, 2008.

A.I.Goncharenko. Sự xuất hiện của bitumen trong đá macma phun trào thuộc Khakasia. Nhà xuất bản Tomsk, Trường Đại học Bách khoa Tomsk. 1992: 160p.

G.C.Fedoseev, V.P.Fadeeva, V.N.Melenevski. Bitumen trong đá dolerite thuộc phức hệ Kuzmenskovo. Tạp chí Địa chất Địa vật lý. 2001; 42(7): p. 1110 - 1117.

O.V.Serebennikova, B.D.Vasilev, Turov Yu.P và nnk. Naphthide trong đá basalt thuộc Devon hạ phía Bắc trũng Minusinskoi. Báo cáo Khoa học. 2003; 390(4): p. 525 - 527.

Kenneth E.Peters, Clifford C.Walters, J.Мichael Moldowan. The biomarker guide: Biomarkers and isotopes in petroleum systems and earth history. Cambridge University Press. 2005: 1115 p.

C.Jacobelli, G.Perez, C.Polcaro, E. Possagno, R.Bassanelli, E. Lilla. Formation of isomeric terphenyls and triphenylene by pyrolysis of benzene. Journal of Analytical and Applied Pyrolysis. 1983; 5(3): p. 237 - 243.

G.Perez, A.Cristalli. Pyrolysis of benzenenaphthalene mixture. Chemosphere. 1991; 22(3-4): p. 279 - 284.

Michael C.Masonjones, Jaideep Mukherjee, Adel F.Sarofim, Kolo Taghizadeh, Arthur L.Lafleur. High temperature pyrolysis of o-terphenyl: Evidence for kinetic control in the benzene polymerization pathway and importance of arene aggregation/Condensation reactions in the formation of polycyclic aromatic hydrocarbons. Polycyclic Aromatic Hydrocarbons. 1996; 8.(1): p. 229 - 242.

R.E.Summons, T.G.Powell. Identification of arylisoprenoids in source rocks and crude oils: Biological markers for the green sulfur bacteria. Geochimica et Cosmochimica Acta. 1987; 51(3): p. 557 - 566.

Published
2014-04-30
How to Cite
Hai, V. V., & Serebrennikova, O. (2014). Studying the composition of hydrocarbons of bitumen in magmatic rocks from North Khakasia (Russia). Petrovietnam Journal, 4, 32-40. Retrieved from https://www.pvj.vn/index.php/TCDK/article/view/559
Section
Articles